![]() A very special 2 player game from the Unblocked games category is appearing right. Show your talent, move in and make the score. Bouncy Basketball Game - Play Now Bouncy Basketball Online on U-Free. You can try famous free 2-Player games such as Basketball Starts, Sports HeadBasketball here. When I’m about to make an amazing shot the Ai somehow get super jumping powers and are able to hop from one side of the court to the order and grab the ball right before it goes in. Free basketball games for kids are right here. Please please pleaseeeee fix it I would be beating the ai with 100 points every game if they would stop goaltending. Another problem playing with AI is the amount of goaltending they do. So it’s either beat the AI by 30+ points in easy mode OR have to deal with AI who never miss their shots and your team somehow turns to garbage even though there 3 circles. Unblocked games 66 66 All Unblocked Games Select a game 1 On 1 Basketball 1. The AI never miss there shots always make 3’s they always steal the ball and when they do they steal the ball from the guy in front yet the guy in back gets the ball even he made no contact whatsoever with the ball or the player. Bloons Tower Defense Unblocked Game Bloons TD is a tower defense game where. ![]() Alright this game is fun to play with friends but the AI in this game are ridiculous once I was getting tired of beating the AI by 30+ points I switched to Hard mode but that mode is impossible. ![]()
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![]() ![]() Changing settings in the BIOS might cause issues with your PC/Laptop. NOTE: These settings are available only for selected laptops. A pop-up will then appear prompting you to restart BlueStacks 5 to begin using your PC's dedicated GPU. This could be due to various reasons controlled by Windows or technical limitations of an older GPU adapter.Ĥ. NOTE: Follow these steps to start using the dedicated GPU if BlueStacks 5 uses your integrated GPU despite selecting the "Prefer dedicated GPU" option with a dedicated GPU installed on your computer. Next, click on the "Save changes" button on the bottom right. Here, ensure that the slider in front of Prefer dedicated GPU is ON, as shown below. In the "Graphics" tab, locate the section "GPU in use". In BlueStacks 5 settings, navigate to the "Graphics" tab, as shown below.ģ. Launch BlueStacks 5 and click on the gear icon on the bottom right to open the settings menu.Ģ. Through the graphics settings on Windowsġ.Here's how you can dedicate your GPU to BlueStacks: How can I dedicate my preferred GPU to BlueStacks 5? NOTE: The settings mentioned below will provide a better gaming experience but may affect the system's overall performance. Also, the settings below are for users who have dual-GPU systems, that is if you have an integrated graphics card and a discrete GPU. This provides for a more enriching graphical experience. Having a higher FPS ensures you have the smoothest animations and minimal latency while playing games, both online and offline.Ģ) After enabling this, users who face lag will notice an increase in performance which allows for a more enjoyable experience inside BlueStacks 5.ģ) You will be able to play your favorite games at the highest settings possible, depending on your choice of GPU. Please contact the moderators of this subreddit if you have any questions or concerns.By following the steps below, you can assign your PC/Laptop's GPU to BlueStacks 5, which will increase the overall performance.ĭedicating your GPU to BlueStacks 5 has the following benefits:ġ) This can provide an FPS boost, allowing you to hit that 60FPS mark in various games. I am a bot, and this action was performed automatically. Thanks for taking the time to help us help you!Īlso, PLEASE remember to change the flair of your post to Solved after you have been helped! Your post has not been deleted - do not re-submit it. If you have met these requirements, you can ignore this comment. ![]() If this is your first time creating a virtual machine, we have a guide on our wiki that covers the important steps. Please also check our FAQ and if you find your question is answered there, PLEASE remove your post or at least change the flair to Solved. Please check Google and the VirtualBox Manual before asking simple questions. PLUS a detailed description of the problem, what research you have done, and the steps you have taken to fix it. * Whether you have installed Guest Additions and/or Host Extensions (this solves 90% of the problems we see) * Whether you have enabled VT-x/AMD-V (applicable to all hosts running 6.1 and above) and disabled HyperV (applicable to Windows 10 Hosts) * The version of VirtualBox you are using This is just a friendly reminder in case you missed it. ![]() ![]() ![]() In both cases, NADPH is the ultimate electron donor, reducing FAD back to FADH 2 in each catalytic cycle. GSH rather than GSSG) by a flavin-dependent enzyme called glutathione reductase.ĭisulfide bridges in proteins can also be directly reduced by another flavin-dependent enzyme called 'thioredoxin'. ![]() Inside the cell, cysteines are kept in their reduced (free thiol) state by a high intracellular concentration of GSH, which in turn is kept in a reduced state (ie. In its reduced (thiol) state, glutathione can reduce disulfides bridges in proteins through the reverse of the above reaction.ĭisulfide bridges exist for the most part only in proteins that are located outside the cell. The end result is that a new cysteine-cysteine disulfide forms at the expense of the disulfide in GSSG. In its oxidized form, glutathione exists as a dimer of two molecules linked by a disulfide group, and is abbreviated 'GSSG'.Ī new disulfide in a protein forms via a 'disulfide exchange' reaction with GSSH, a process that can be described as a combination of two S N2-like attacks. In its reduced (free thiol) form, glutathione is abbreviated 'GSH'. Recall that the important functional group in glutathione is the thiol, highlighted in blue in the figure below. The redox agent that mediates the formation and degradation of disulfide bridges in most proteins is glutathione, a versatile coenzyme that we have met before in a different context ( section 14.2A). Notice that in the oxidized (disulfide) state, each sulfur atom has lost a bond to hydrogen and gained a bond to a sulfur - this is why the disulfide state is considered to be oxidized relative to the thiol state. The interconversion between thiols and disulfide groups is a redox reaction: the thiol is the reduced state, and the disulfide is the oxidized state. Table 18.1, below, provides a quick comparison of oxygen-containing and sulfur-containing organic compounds.ĭisulfide (sulfur-sulfur) linkages between two cysteine residues are an integral component of the three-dimensional structure of many proteins. You need not memorize the methods used to carry out these oxidations. sulfoxides and sulfones are obtained by oxidizing organic sulfides. Later we shall see examples of tetraalkylammonium ions, R 4N +, which again may be regarded as being similar to hydronium ions. If you have trouble understanding why trialkylsulfonium ions are formed, think of them as being somewhat similar to the hydronium ions that are formed by protonating water: Thiolate anions are better nucleophiles than are alkoxy anions (see Section 11.5, pages 389-394 of the textbook). Thiolate anions, RS-, are analogous to alkoxy anions, RO. ![]() For example, SO 4 2 − is the sulfate ion while S 2O 3 2 −, in which one of the oxygen atoms of a sulfate ion has been replaced by a sulfur atom, is called thiosulfate. Notice that the term “thio” is also used in inorganic chemistry. The nomenclature of sulfides can be easily understood if one understands the nomenclature of the corresponding ethers. (Organic) sulfides have the structure R-S-R′, and are therefore the sulfur analogues of ethers. A disulfide is a compound containing an -S-S- linkage. The -SH group itself is called a mercapto group. ![]() A thiol is a compound which contains an SH functional group. However, we have included a short section on these compounds, not for the sake of increasing the amount of material to be digested, but because much of the chemistry of these substances can be predicted from a knowledge of their oxygen-containing analogues. The chemistry of sulfur-containing organic compounds is often omitted from introductory organic chemistry courses.
![]() In Short: We process your information for purposes based on legitimate business interests, the fulfillment of our contract with you, compliance with our legal obligations, and/or your consent. Examples of the information we receive from other sources include: social media profile information marketing leads and search results and links, including paid listings (such as sponsored links). We may obtain information about you from other sources, such as public databases, joint marketing partners, as well as from other third parties. In Short: We may collect limited data from public databases, marketing partners, and other outside sources. You can find out more about this in our Cookies Policy. Like many businesses, we also collect information through cookies and similar technologies. This information is primarily needed to maintain the security and operation of our Sites, and for our internal analytics and reporting purposes. This information does not reveal your specific identity (like your name or contact information) but may include device and usage information, such as your IP address, browser and device characteristics, operating system, language preferences, referring URLs, device name, country, location, information about how and when you use our Sites and other technical information. ![]() We automatically collect certain information when you visit, use or navigate the Sites. In Short: Some information – such as IP address and/or browser and device characteristics – is collected automatically when you visit our Sites. All payment data is stored by our payment processor and you should review its privacy policies and contact the payment processor directly to respond to your questions.Īll personal information that you provide to us must be true, complete and accurate, and you must notify us of any changes to such personal information. We collect data necessary to process your payment if you make purchases, such as your payment instrument number (such as a credit card number), and the security code associated with your payment instrument. We collect passwords, password hints, and similar security information used for authentication and account access. We collect your first and last name, email address, postal address, phone number, and other similar contact data.Ĭredentials. The personal information we collect can include the following: The personal information that we collect depends on the context of your interactions with us and the Sites, the choices you make and the products and features you use. We collect personal information that you voluntarily provide to us when registering at the Sites expressing an interest in obtaining information about us or our products and services, when participating in activities on the Sites or otherwise contacting us. In Short: We collect personal information that you provide to us such as name, address, contact information, passwords and security data, and payment information.
![]() ![]() If we allow them to age, our faces will tell our life story. In the contemporary world, faces are often a blank canvas to be manipulated with cosmetic surgery, injections, and intricate makeup techniques learned on YouTube. Other cultures draw attention to faces with displays of tattoos, piercings, and scarification. In some cultures, faces are veiled and hidden. Faces root us in our culture, in the rituals and rules about how we present ourselves and how we see others. Our faces are the outer image we attach to our inner sense of self, to who we are and where we fit in the world. What do you see? Most of us would answer, “Myself.” Right: Adrea Schneider, the donor, in 2017. Faces, in evolutionary terms, helped us become social animals. This close study of faces is the way we all begin to understand the curious business of being human. Babies observe, respond to, and mimic our expressions as though it’s their job. Newborns turn toward them during their first moments out of the womb. Faces are the body’s workaholics: They confer and confirm identity, express emotion, communicate meaning, perform basic functions necessary for life, and enable us to experience the world through our senses. Our faces are the most distinctive part of our visible body, a mysterious mosaic of the physical and the psychical. Only humans are known to express dismay when looking at their reflections.Īs we scrutinize our own faces for wrinkles and flaws, we can fail to notice what a marvelous organ the face is. Dolphins as young as seven months will pose, twirl, and put their eye right up against the mirror to stare at their faces. Besides us, great apes, Asian elephants, Eurasian magpies, and bottlenose dolphins are the only other animals known to recognize themselves. We are members of an exclusive group: animals that recognize their own faces in a mirror. He says a silent prayer of thanks and takes the face to its next life. ![]() It’s an amazing thing, he thinks, what some people will do for others-to give them a heart or a liver, even a face. Looking down at the face he carries, Papay feels a kind of reverence. Her transplant, the clinic’s third and the 40th known in the world, will be one of the most extensive, making her a lifelong subject in the study of this still experimental surgery. Katie will be the youngest person to receive a face transplant in the United States. With each second of detachment, it looks more like a 19th-century death mask.įrank Papay, a veteran plastic surgeon, picks up the tray, carrying it carefully in his gloved hands, and walks to Operating Room 20, where Katie Stubblefield waits. Surgeons, residents, and nurses, suddenly silent, gaze at it in awe as clinic staff, like unusually polite paparazzi, move in with cameras to document it. Soon they will take it to a 21-year-old woman who has waited more than three years for a new face.įor a moment, the face rests in its astonished solitude. Sixteen hours ago surgeons in Operating Room 19 at the Cleveland Clinic began the delicate work of removing the face from a 31-year-old woman who was declared legally and medically dead three days earlier. The face lies on a surgical tray, eyes empty and unseeing, mouth agape, as if exclaiming, “Oh!” This story appears in the September 2018 issue of National Geographic magazine. This is a story of trauma, identity, resilience, devotion, and amazing medical miracles. When she was 21, doctors gave Katie a new face. Are we our faces? Katie Stubblefield lost hers when she was 18. It’s our doorway to the sensory world, allowing us to see, smell, taste, hear, and feel the breeze. Our face conveys who we are, telegraphing a kaleidoscope of emotions. Yet we are asking you to go on the remarkable journey of how a young woman received a face transplant because it reveals something profound about our humanity. ![]() ![]() ![]()
![]() ![]() Twitch Partner: To unlock the path to partnership, you must first become a Twitch Affiliate.Affiliate program: You need at least 500 total minutes broadcast in the last 30 days, at least 7 unique broadcast days in the last 30 days, an average of 3 concurrent viewers or more over the last 30 days, and at least 50 Followers. This program allows you to receive bits, accept subscriptions and sell Twitch products for a commission.One of the most interesting options on Twitch is that you can earn money through donations from your followers: You can consult our dedicated guide about how to broadcast video on Twitch using OBS from your computer or smartphone. ![]() If you want a more versatile but complex solution, give OBS Studio a try. If you want the quickest way to broadcast on Twitch, you can use Twitch Studio.Buy bits and rewards that you can then send to content creators to support them. Create your own list of favorite channels.Subscribe to channels and start chatting with a new community.Follow other users, friends, or celebrities, and explore the different channels you want to follow using the filters.Then, select your video content preferences so Twitch can start recommending channels matching your taste.Once Twitch is downloaded and installed, you can create an account and log in using the required information, enter the verification code you receive by email, and complete your registration.When a stream you like is about to start, you will receive proper notifications. Notifications: Never miss your favorite streamers through alerts and saved channels.Besides, by using categories, you can efficiently browse your channels and focus on the kind of content you like. Find your communities: On Twitch, you will find huge communities with the same interests and hobbies as you, and you will be able to chat, comment and learn with them.Extensions: You can customize your Twitch experience by using many app-or-product-specific extensions like Prime Gaming or Spotify playlists, add scoreboards, or more complex social tools to translate content, add polls, and much more.As streamers can include it in their stream, it is super handy to increase the engagement level of viewers, and it is really effective to create unique shared moments. Interact lively: You can directly send instant messages to creators and other users through live chat.Indeed, feel free to browse all the different ones, like IRL (just chatting, talk shows, podcasts), Music, Esports, Games, or Creative. Huge catalog: Even though it is mainly about games, there are lots of different categories on Twitch, making it the most diversified live-streaming content platform.Furthermore, you have access to many different tools like Analytics, you can archive your videos, and can even use Twitch Studio to create content easily. Once you've built up enough of a reputation, you can start monetizing your content and making a living from it (also, viewers can make donations, and you can perceive money through affiliation). Become a streamer: Using a camera and a microphone, you can start steaming right now and create your own community of viewers.For some people, Twitch is now the way they make money and express their creativity. Launched in 2011, Twitch has become a giant in the live-streaming industry and reunites content creators and viewers to create unique moments of sharing and entertainment. The Twitch Desktop App also features CurseForge, the legendary game mod community where thousands of mods and addons are shared for World of Warcraft, Skyrim, Minecraft, and tons more games.Twitch is an American video live-streaming service for video game live streaming, and esports competitions, but also offers music broadcast or content for in-real-life streams. On Twitch web, you can private message your friends with Whispers, but in the desktop app you can also get personal with voice and video calls! Mods and Addons Speaking of friends, with the Twitch Desktop App’s Friend Sync, we’ll help you find all your friends from across the creator-verse. Dark Modeĭark mode makes everything you do on Twitch much more friendly to your eyes. But with Twitch Desktop App’s servers, communities have a place to call home 24/7 with text and voice rooms. When a stream goes offline, so does its community… sadness. The Twitch Desktop App also brings a powerful arsenal of features you won’t find on the web: Dark Mode, voice and video calls, servers, friend sync, and even a ton of great mods for your games. While you’re watching, you can even support the streamers you love with Subscriptions and Bits. ![]() Watch all your favorite VODs, clips, and of course, live streams, complete with Twitch chat in all its glory. Plus, because it’s an app, it’s all lightning fast. From streams to memes, everything you love about Twitch on web is available within the desktop app. ![]() ![]() ![]() Click the AdBlocker Ultimate icon in the browser extension area in the upper right-hand corner.“ Block ads on – This website” switch off the toggle to turn it from blue to gray.Click the AdBlock Plus icon in the browser extension area in the upper right-hand corner.Refresh the page or click the button below to continue.Under “ Pause on this site” click “ Always”. ![]() Click the AdBlock icon in the browser extension area in the upper right-hand corner.In case you missed it, we looked back at the best Mario games of all time for this year’s celebration of Mario Day.Īdblock Adblock Plus Adblocker Ultimate Ghostery uBlock Origin Others For those interested in emulating titles right away, you can download the emulator from Dolphin’s website. The store page for the Dolphin Emulator is now live on Steam with a planned early access release taking place by the end of quarter two of this year at an always-free price point. Once you’re bored of a game, you can breathe new life into it by playing community-made mods like randomizers and custom level packs.” You can even take your favorite local multiplayer games online with Dolphin’s built-in netplay. While playing a game, features like quick saves (save states), slow motion, and turbo can make playing through annoying sections a breeze. Key perks of emulation include the following outlined by Dolphin: “Increased resolution, widescreen hacks, HD texture packs, and patches to increase the frame rate. It’s important to note that users will need to provide their own ROMs - the memory needed to emulate a game - however, it will increase the availability of emulation - including future Steam Deck integration. Now, it has announced that it a Steam version of its emulator is on the way. Dolphin Emulator has been a go-to for emulating the Nintendo GameCube and Wii consoles for years. For many gamers, they’ve turned to emulators as the best option for revisiting games. ![]() ![]() ![]() Got a question? Or want help, suggestions, travel tips, learn how to travel for free, find out about travel deals, and maximize your miles and points? Use the subscription box below to sign-up and get post updates by email.Arrived in Las Vegas on 10/13/19 claimed my bags in baggage claim and walked out the glass doors to catch a shuttle to my hotel. Pin this to your Las Vegas, travel, vacation or hotel board:įollow us on Twitter | Facebook | Pinterest | Instagram | YouTube ![]() What’s your pick for the best hotel in Las Vegas? You also get free Wi-Fi, parking, and pay no resort fees! Plus there’s a shuttle to take you the strip. It’s one of the few hotels that offer free breakfast and a free airport shuttle.
![]() However, the inclusion of ads and a 25-file limit is certainly not bad for a free solution. If you don't want to pay for your PDF merger, then this is the tool to go for.Īpple Preview is arguably the best PDF merge software for Mac - if only because it's free and comes pre-installed on all modern Macs.īuilt by Apple, the PDF manipulator isn't quite as feature-filled as rivals such as Adobe Acrobat and Nitro PDF Pro. But when we tested out the software, we were delighted with the results. "One of the best PDF readers on the Mac which also comes with powerful editing functions," we wrote in our review, "Apple’s Preview should be able to cater to all but the most demanding PDF road warriors." The first-party PDF software houses plenty of tools, including an elegant PDF merger and the option to simply and seamlessly combine PDFs. When it comes to PDF editing, Apple Preview is slightly lacking. It's mostly limited to reordering, rotating, and removing pages from documents. And there’s no way to edit PDF text here.īut if you're a Mac owner who needs to swiftly merge PDF files, Apple Preview makes the job a breeze. ![]() PDF Converter is a reliable PDF merger that can handle most of your file needs. You can merge PDFs, Word documents, images, and more through seamless conversion. The web-based merge tool is easy to use and enables you to drag and drop files to reorder them. When you’re done, you can compress your new PDF to save space on your hard drive. The catch to this tool is that its name is misleading. ![]() PDF Converter allows you to conduct just one merge for free per hour. So, once you merge files, you’ll need to wait 60 minutes before you can merge any more unless you purchase a Premium subscription. ![]() |
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